Boydston Research Group
UW-Madison Department of Chemistry

100th Anniversary of Macromolecular Science Viewpoint: Integrating Chemistry and Engineering to Enable Additive Manufacturing with High-Performance Polymers

Posted on

Additive manufacturing (AM) with high-performance polymers (HPPs) represents simultaneously one of the most desirable and challenging feats in the AM arena. The very properties that make HPPs so attractive in a broad range of applications also make them nearly impossible to process using common AM equipment. Furthermore, when AM is achieved, it often brings the caveat of compromised mechanical properties of the final parts, in comparison with those made via injection molding. The demand to have advanced fabrication methods, rapid prototyping, and customization of parts while maintaining high performance in the finished products has inspired creative innovations that integrate chemical synthesis, materials science, mechanical engineering, and other fields into a multidisciplinary approach to advance AM with the seemingly “unprintable” HPPs. In this Viewpoint, we summarize several standout developments in the area and offer our perspective on future directions and challenges.

Synthesis and characterization of anionic poly(cyclopentadienylene vinylene) and its use in conductive hydrogels.

Posted on

The use of π‐conjugated polymers (CPs) in conductive hydrogels remains challenging due to the water‐insoluble nature of most CPs. Conjugated polyelectrolytes (CPEs) are promising alternatives because they have tunable electronic properties and high water‐solubility, but they are often difficult to synthesize and thus have not been widely adopted. Herein, we report the synthesis of an anionic poly(cyclopentadienylene vinylene) (aPCPV) from an insulating precursor under mild conditions and in high yield. Functionalized aPCPV is a highly water‐soluble CPE that exhibits low cytotoxicity, and we found that doping hydrogels with aPCPV imparts conductivity. We also anticipate that this precursor synthetic strategy, due to its ease and high efficiency, will be widely used to create families of not‐yet‐explored π‐conjugated vinylene polymers.